Here is a list, in order of "most polyphenols" from your chocolate:
1. Cocoa powder (pure, no sugar or any other additives)
2. unsweetened baking chocolate
3. Semi-sweet chocolate baking chips
4. Dark Chocolate (this could be higher on the list depending the %)
5. Chocolate syrup
6. Milk chocolate (doesn't have much so I would just go straight for the dark)
After trying chocolate "nibs," which are basically the cocoa "meat" straight from the shell, I have much respect for anyone who can do this. I believe you can purchase these at PCC and Whole Foods in Seattle - bulk section - so give it a try. I dare you. Even a 90% dark chocolate bar is difficult to eat more than a bit of...
Good luck!
P.S. Cocoa powder is high in copper and potassium. In fact, America's main source of dietary copper comes from chocolate. Wow.